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jetJagger
Toy Prince
Joined: Tue Apr 11, 2006 3:17 am Posts: 401
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 Qualty of Marmit Vinyl
I've got a Marmit figure from 2004 that's already getting 'gummy' or 'clammy' or whatever word you would use to described that light stickiness you can feel on vinyl or plastic as it begins to break down.
Anyone else have this experience with Marmit figures? Or is it (hopefully) just the batch for this figure?
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| Fri Jul 16, 2010 9:08 am |
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Rich
Die-Cast
Joined: Tue Mar 07, 2006 8:46 pm Posts: 11806
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 Re: Qualty of Marmit Vinyl
It sort of happens, a nice wet cloth should take the residue off. Usually a good wipe down every few months can't hurt 
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| Fri Jul 16, 2010 10:50 am |
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Cubensis
Line of Credit
Joined: Tue Sep 29, 2009 3:30 pm Posts: 1814 Location: Middltown, CT
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 Re: Qualty of Marmit Vinyl
I get this on my Shaved Ice Boogie. Was never really sure why.
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| Fri Jul 16, 2010 12:15 pm |
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bryce_r
Vintage
Joined: Wed Aug 15, 2007 10:57 am Posts: 7991 Location: SanJose
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 Re: Qualty of Marmit Vinyl
Cubensis wrote: I get this on my Shaved Ice Boogie. Was never really sure why. It doesn't surprise me that the bukkaked looking boogie has this problem.
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| Fri Jul 16, 2010 1:19 pm |
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akum6n
Prototype
Joined: Sat Nov 04, 2006 12:03 am Posts: 6162 Location: Shima
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 Re: Qualty of Marmit Vinyl
I've had this on other stuff- Bear Model, Gargamel. Clear vinyl seems to be the most susceptible to the problem.
Wet cloth does not help. Sometimes dish soap and water will clean it up a bit, but I rarely do that unless they are unpainted and easy to disassemble.
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| Fri Jul 16, 2010 8:17 pm |
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JAY
Super Deformed
Joined: Thu Jul 05, 2007 4:51 pm Posts: 5906 Location: Manila, Philippines
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 Re: Qualty of Marmit Vinyl
Some Buta No Hana figs too get this stickyness.
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| Fri Jul 16, 2010 8:25 pm |
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turtletooth
Post Pimp
Joined: Thu Mar 16, 2006 8:19 am Posts: 2683 Location: Dirty Jersey
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 Re: Qualty of Marmit Vinyl
I wait until they get really tacky and then roll them in toasted coconut.
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| Fri Jul 16, 2010 8:25 pm |
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il_muffino
Addicted
Joined: Wed Jun 06, 2007 8:32 pm Posts: 835 Location: San Francisco
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 Re: Qualty of Marmit Vinyl
bryce_r wrote: Cubensis wrote: I get this on my Shaved Ice Boogie. Was never really sure why. It doesn't surprise me that the bukkaked looking boogie has this problem. That's naaaaasty.
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| Fri Jul 16, 2010 8:39 pm |
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TULKU
Addicted
Joined: Fri Jan 01, 2010 10:00 pm Posts: 518
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 Re: Qualty of Marmit Vinyl
I have some older Marmit from 1996 that's holding very well. I notice the effect you speak of on any vinyl that's 'dirty' from whatever is on peoples hands from handling, oil etc.... I am not sure if the older collectors on the board would condone this but I use 100% pure alcohol wipe pads for a thorough wipe down (do not use other kinds of wipes), as long as the paint is not cheap garbage it does no damage at all. It kills bacteria and gets rid of oil then simply evaporates. After that I make sure I wash my hands before handling. Of course a wet non abrasive soft towel is the safest maintenance program.
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| Fri Jul 16, 2010 8:57 pm |
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m3kcomp
Side Dealer
Joined: Wed Aug 08, 2007 11:56 am Posts: 2234 Location: Cloud 149
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 Re: Qualty of Marmit Vinyl
bryce_r wrote: Cubensis wrote: I get this on my Shaved Ice Boogie. Was never really sure why. It doesn't surprise me that the bukkaked looking boogie has this problem. the day that it dropped felt like a circle jerk, so it's appropriately decorated and named. then everyone sold theirs to someone else...the damaged goods bukkake boogie.
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| Fri Jul 16, 2010 9:12 pm |
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COOP
Comment King
Joined: Mon Feb 22, 2010 9:18 am Posts: 1357 Location: Los Angeles
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 Re: Qualty of Marmit Vinyl
Squirt 'em with some simple green, then rinse 'em off in the sink. Supposedly you can drink that stuff, so it should be safe for your japanese bath toys.
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| Fri Jul 16, 2010 10:09 pm |
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melek_taus
Mini Boss
Joined: Mon Aug 06, 2007 4:48 pm Posts: 4668 Location: Where the brightest angel fell.
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 Re: Qualty of Marmit Vinyl
But then your toy smells like Simple Green. Yuck.
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| Fri Jul 16, 2010 10:28 pm |
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COOP
Comment King
Joined: Mon Feb 22, 2010 9:18 am Posts: 1357 Location: Los Angeles
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 Re: Qualty of Marmit Vinyl
Not after you rinse it off.
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| Fri Jul 16, 2010 10:31 pm |
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melek_taus
Mini Boss
Joined: Mon Aug 06, 2007 4:48 pm Posts: 4668 Location: Where the brightest angel fell.
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 Re: Qualty of Marmit Vinyl
I guess. I just wouldn't want to risk ruining my toy's toxic, vinyl chemical smell with that Simple Green smell. Call me paranoid. 
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| Sat Jul 17, 2010 1:14 am |
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VELOCITRON
Comment King
Joined: Wed Mar 19, 2008 6:49 pm Posts: 1437 Location: BURST CITY
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 Re: Qualty of Marmit Vinyl
Vinyl is an oil-based product and because of that you do get some "sweating" periodically. Clear and GID (which is really just clear with GID powder suspended in it) are definitely the worst culprits. Usually I have to wipe all GID vinyl from the factory off before I paint it because its kind of slimy. That would also explain why water doesn't do much, since it's basically a fight between oil and water.
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| Sat Jul 17, 2010 2:34 am |
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Cubensis
Line of Credit
Joined: Tue Sep 29, 2009 3:30 pm Posts: 1814 Location: Middltown, CT
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 Re: Qualty of Marmit Vinyl
I've only been collecting JP vinyl for a few years, but talk of degradation makes me think about the long haul... the condition they will be in decades from now. If this periodic "sweating" and inevitable degradation occurs to vinyl, will my toys be shapeless, sticky blobs 60 years from now? Will they eventual soften and start drooping and such? Of course, I am also implying that they are kept out of direct sunlight and in a safe environment during this time.
I mean, wear and tear from playing aside, Astro-Mu, Bullmark, and other toys from the 60's and 70's seem to still be doing all right in terms of vinyl life. Maybe I'm just way over thinking, but it's a question that has come to mind at least a few times. Anybody have any input?
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| Sat Jul 17, 2010 9:09 am |
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COOP
Comment King
Joined: Mon Feb 22, 2010 9:18 am Posts: 1357 Location: Los Angeles
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 Re: Qualty of Marmit Vinyl
Cubensis wrote: I've only been collecting JP vinyl for a few years, but talk of degradation makes me think about the long haul... the condition they will be in decades from now. If this periodic "sweating" and inevitable degradation occurs to vinyl, will my toys be shapeless, sticky blobs 60 years from now? Will they eventual soften and start drooping and such? Of course, I am also implying that they are kept out of direct sunlight and in a safe environment during this time.
I mean, wear and tear from playing aside, Astro-Mu, Bullmark, and other toys from the 60's and 70's seem to still be doing all right in terms of vinyl life. Maybe I'm just way over thinking, but it's a question that has come to mind at least a few times. Anybody have any input? Yeah, my 40-year-old Bullmarks are doing just fine, and the newer stuff is probably made from better vinyl to boot.
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| Sat Jul 17, 2010 10:36 am |
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COOP
Comment King
Joined: Mon Feb 22, 2010 9:18 am Posts: 1357 Location: Los Angeles
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 Re: Qualty of Marmit Vinyl
melek_taus wrote: I guess. I just wouldn't want to risk ruining my toy's toxic, vinyl chemical smell with that Simple Green smell. Call me paranoid.  Don't worry, they still smell like toxic plastic.
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| Sat Jul 17, 2010 10:37 am |
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akum6n
Prototype
Joined: Sat Nov 04, 2006 12:03 am Posts: 6162 Location: Shima
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 Re: Qualty of Marmit Vinyl
COOP wrote: ...
Yeah, my 40-year-old Bullmarks are doing just fine, and the newer stuff is probably made from better vinyl to boot. Actually, I disagree. I think the new clear vinyls are even more unstable than the old ones- maybe because the material is softer and has greater clarity. I left one of my clear Blobpus guys in the sealed jar for a year or so, and the inside of the jar ended up covered in a thin film of oil. The solid colors might fare similarly to the old stuff. A lot of it probably has to do with storage and display environmental conditions. But some vinyls have degraded despite being kept in identical storage/display situations as other comparable vinyls which have not changed at all. So I don't know.
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| Sat Jul 17, 2010 10:44 am |
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COOP
Comment King
Joined: Mon Feb 22, 2010 9:18 am Posts: 1357 Location: Los Angeles
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 Re: Qualty of Marmit Vinyl
Interesting. I've only had one new vinyl "sweat" like that (an M1GO Titanosaurus) and after I hit it with the Simple Green, it was fine.
Is it possibly some kind of mold release or something? I know nothing about the chemical makeup of these things.
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| Sat Jul 17, 2010 10:51 am |
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onibaba5
Post Pimp
Joined: Mon Oct 02, 2006 10:30 am Posts: 2954 Location: Hudson, Ohio
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 Re: Qualty of Marmit Vinyl
jetJagger wrote: I've got a Marmit figure from 2004 that's already getting 'gummy' or 'clammy' or whatever word you would use to described that light stickiness you can feel on vinyl or plastic as it begins to break down.
Anyone else have this experience with Marmit figures? Or is it (hopefully) just the batch for this figure? Vinyl or abs figures made with recycled plastic tend to excrete an oily substance. It's pretty common. The early Medicom 400% vinyl Be@rbricks had this problem before they went to unrecycled ABS plastic. Not sure if it's the same problem you are having but fyi...
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| Sat Jul 17, 2010 10:55 am |
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Biff
S7 Royalty
Joined: Fri Jun 16, 2006 6:19 pm Posts: 3442
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 Re: Qualty of Marmit Vinyl
Leaving toys in their bags seems to exacerbate the 'sweating'. Or maybe the sweat just evaporates a bit w/ open toys.
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| Sat Jul 17, 2010 11:23 am |
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COOP
Comment King
Joined: Mon Feb 22, 2010 9:18 am Posts: 1357 Location: Los Angeles
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 Re: Qualty of Marmit Vinyl
Biff wrote: Leaving toys in their bags seems to exacerbate the 'sweating'. Or maybe the sweat just evaporates a bit w/ open toys. Another good reason to set those toys free!
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| Sat Jul 17, 2010 12:00 pm |
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rotokirby
Toy Prince
Joined: Fri Jun 23, 2006 2:54 pm Posts: 240
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 Re: Qualty of Marmit Vinyl
In most cases the oily substances that accumulate on the surface of vinyl over time are chemical plasticizers or other additives used to change the properties of the base PVC (polyvinyl chloride, aka vinyl). They make it softer, clearer, etc. If toys were made with straight PVC without plasticizers they would be very, very hard (think PVC pipe...it's the same stuff, just with different plasticizers than the ones used to make vinyl soft for toys). The thing to remember is that vinyl is essentially "breathing" all the time...if you seal it in something and leave it there long enough you're probably going to see some sort of residue eventually. Of course it changes from batch to batch, factory to factory. And Ralph, I think you're onto something with the idea that perhaps recycled vinyl may be part of the issue. In the end, the fact is that vinyl is complex, and sometimes the various parts just don't want to stay together. This is a pretty good overview of the history and manufacturing of vinyl: http://www.azom.com/Details.asp?ArticleID=987
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| Sat Jul 17, 2010 1:47 pm |
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Habbit
Toy Prince
Joined: Sun Sep 28, 2008 7:45 am Posts: 211 Location: Crooklyn
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 Re: Qualty of Marmit Vinyl
rotokirby wrote: The thing to remember is that vinyl is essentially "breathing" all the time...if you seal it in something and leave it there long enough you're probably going to see some sort of residue eventually. Of course it changes from batch to batch, factory to factory. And Ralph, I think you're onto something with the idea that perhaps recycled vinyl may be part of the issue. In the end, the fact is that vinyl is complex, and sometimes the various parts just don't want to stay together. This is a pretty good overview of the history and manufacturing of vinyl: http://www.azom.com/Details.asp?ArticleID=987Great link about the history and chemistry of vinyl. Appeals to the kaiju & record geek in me. In regards to kaiju, I figured the vinyl was outgassing something toxic. Much like a lot of toys by say... Neca & Mezco do when you 1st open up the packaging (ahhhhh reminds me of gas stations when they used to reek...). I've never been too worried about kaiju degrading much over time, I figure just about anything I own will outlast me, esp if it's plastic.
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| Sat Jul 17, 2010 3:50 pm |
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